While you're levelling, test out all the weapons. You're already using S/D, so try out S/P, D/D and D/P as well, along with Shortbow, just to see how they play. When deciding what elite to aim for first, how well you're enjoying what you have should be a factor. Daredevil introduces Staff, which is a very strong melee option. If the current melee options for Thief don't really capture your interest, then Staff might be the improvement you need. On the other hand, if you're enjoying your play with mainhand Sword or mainhand Dagger, then consider Deadeye. While it introduces Rifle as a ranged weapon, most gameplay in GW2 should be focused on melee, so you'd still mainly be using Sword or Dagger as a Deadeye, just with the enhancements given by Deadeye's Mark to give you a lot of Quickness and improved stealth attacks, among other things. You can test either of these elite specs out in the PvP lobby, as long as you own the expansions. In PvP, you can set elite specs before you've unlocked them in PvE, so you can try out the new weapons and traits there on training dummies or even on NPCs in the lobby, without actually needing to play PvP games. A handful of traits might have differences between PvE and PvP, but you should get the gist of it.